Category Archives: water

Most flushable wipes aren’t flushable.

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I’m a chemical engineer running for Oakland county water resources commissioner, and as the main job of the office is sewage, and as I’ve already written on the chemistry, I thought I might write about an aspect of the engineering. Specifically about toilet paper. Toilet paper is a remarkable product: it’s paper, compact and low in cost; strong enough to clean you, smooth on your bum, and beyond that, it will disintegrate in turbulent water so it doesn’t clog pipes. The trick to TP’s dry strength and wet-weakness, is that the paper pulp, wood cellulose, is pounded very thin, yet cast fluffy. For extra softness, the paper is typically coated with aloe or similar. Sorry to say, the same recipe does not work for wet-wipes, paper towels or kleenex (facial tissues); all of these products must have wet-strength, and this can cause problems with sewer clogs.

Patent 117355 for perforated toilet paper claimed it as an improved wrapping paper.

Patent 117,355 for perforated toilet paper on a roll. It’s claimed as an improved wrapping paper.

Before there was toilet paper, the world was a much sadder, and smellier place. Much of the world used sticks, stones, leaves, or corn cobs, and none of these did a particularly thorough job. Besides, none of these is particularly smooth, or particularly disposable, nor did it fall apart — not that most folks had indoor plumbing. Some rich Romans had plumbing, and these cleaned themselves with a small sponge on the end of a stick. They dipped the sponge end in water for each use. It was disgusting, but didn’t clog the pipes. I’ve seen this in use on a trip to Turkey 25 years ago — not in actual use, but the stick and sponge was there in a smelly bucket next to the hole in the ground that served as the commode.

The first reasonably modern toilet was invented in 1775 by Alexander Cummings, and by 1852 the first public flush toilets were available. The design looked pretty much like it looks today and the cost was 1¢. You got a towel and a shoe-shine too for that penny, but there was no toilet paper as such. Presumably one used a Roman sponge or some ordinary, standard paper. A popular wipe, back in the day was the Sears-Roebuck catalog. It came free to most homes and included a convenient hole in the corner allowing one to hang it in and outhouse or near the commode. It was rough on the bum, and didn’t fall apart. My guess is that it clogged the pipes too, for those who used it with flush toilets. The first toilet-specific paper wasn’t invented till 1859. Joseph Gayetty, an American, patented a product from pulverized hemp, a relatively soft fiber, softened further with aloe. This paper was softer than standard, and had less tendency to clog pipes.

Toilet paper has to be soft

Toilet paper is either touted to be soft or strong; Modern Charmin touts wet strength, while Cottonelle touts completeness of wipe: ‘go commando.”

The next great innovation was to make toilet paper as a perforated product on a roll. These novelties appear as US Patent #117,355 awarded to Seth Wheeler of Albany, NY 25 July 1871 (Wheeler also invented the classic roll toilet paper dispenser). Much of the sales pitch was that a cleaner bum would prevent the spread of cholera, typhoid, and other plagues and that is a legitimate claim. As the  market expanded, advertising followed. Some early brands touted their softness, others their strength. Facial tissues, e.g. Kleenex, were sold specifically as a soft TP-like product that does not fall apart when wet. Sorry to say, this tends to go along with clogged toilets; do not flush more than one kleenex down at a flush. Kleenex is made with the same short fibers and aloe as toilet paper, but it contains binders (glue) to give it wet-strength. My guess is that Charmin is made the same way and that it isn’t great on your plumbing.

Paper towels and most baby wipes are worse to flush than Kleenex. They are made with lots of binder and they really don’t fall apart in water. Paper towels should never be flushed, and neither should most baby wipes, even brands that claim to be ‘flushable.” When flushed, these items tend to soak up fat and become fat bergs – the bane of sewer workers everywhere. There is a class action law suit against flushable wipe companies, and New York City is pursuing legislation to prevent them from claiming to be flushable. Still, as with everything, there are better and worse moist-wipe options. “Cottonelle” brand by Kleenex, and Scott flushable wipes are the best currently. In a day or less they will dissolve in water. These products are made with binders like kleenex, but the binder glue is a type that dissolves in any significant amount of water. As a result, these brands fall apart eventually. For now, these are the only flushable brands I’d recommend flushing, and even then I suggest you only flush one at a time. In tests by Consumer Reports, other brands, e.g. Charmin and Equate flushable wipes do not dissolve. These manufacturers either have not quite figured out how to make dissolvable binders, or they can’t get around Kleenex’s patents.

Robert Buxbaum. October 10, 2016. If you live in Oakland County, MI, vote for me for water commissioner. Here’s my web-site with other useful essays. I should mention Thomas Crapper, too. He invented the push-button flush and made some innovations in the water cistern, and he manufactured high-end commodes for Parliament and the royal family, but he’s irrelevant to the story here.

just water over the dam

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Some months ago, I posted an engineering challenge: figure out the water rate over an non-standard V-weir dam during a high flow period (a storm) based on measurements made on the weir during a low flow period. My solution follows. Weir dams of this sort are erected mostly to prevent flooding. They provide secondary benefits, though by improving the water and providing a way to measure the flow.

A series of weir dams on Blackman Stream, Maine. These are thick, rectangular weirs.

A series of compound, rectangular weir dams in Maine.

The problem was stated as follows: You’ve got a classic V weir on a dam, but it is not a knife-edge weir, nor is it rectangular or compound as in the picture at right. Instead it is nearly 90°, not very tall, and both the dam and weir have rounded leads. Because the weir is of non-standard shape, thick and rounded, you can not use the flow equation found in standard tables or on the internet. Instead, you decide to use a bucket and stopwatch to determine the flow during a relatively dry period. You measure 0.8 gal/sec when the water height is 3″ in the weir. During the rain-storm some days later, you measure that there are 12″ of water in the weir. Give a good estimate of the storm-flow based on the information you have.

A V-notch weir, side view and end-on.

A V-notch weir, side view and end-on.

I also gave a hint, that the flow in a V weir is self-similar. That is, though you may not know what the pattern will be, you can expect it will be stretched the same for all heights.

The upshot of this hint is that, there is one, fairly constant flow coefficient, you just have to find it and the power dependence. First, notice that area of flow will increase with height squared. Now notice that the velocity will increase with the square root of hight, H because of an energy balance. Potential energy per unit volume is mgH, and kinetic energy per unit volume is 1/2 mv2 where m is the mass per unit volume and g is the gravitational constant. Flow in the weir is achieved by converting potential height energy into kinetic, velocity energy. From the power dependence, you can expect that the average v will be proportional to √H at all values of H.

Combining the two effects together, you can expect a power dependence of 2.5 (square root is a power of 0.5). Putting this another way, the storm height in the weir is four times the dry height, so the area of flow is 16 times what it was when you measured with the bucket. Also, since the average height is four times greater than before, you can expect that the average velocity will be twice what it was. Thus, we estimate that there was 32 times the flow during the storm than there was during the dry period; 32 x 0.8 = 25.6 gallons/sec., or 92,000 gal/hr, or 3.28 cfs.

The general equation I derive for flow over this, V-shaped weir is

Flow (gallons/sec) = Cv gal/hr x(feet)5/2.

where Cv = 3.28 cfs. This result is not much different to a standard one  in the tables — that for knife-edge, 90° weirs with large shoulders on either side and at least twice the weir height below the weir (P, in the diagram above). For this knife-edge weir, the Bureau of Reclamation Manual suggests Cv = 2.49 and a power value of 2.48. It is unlikely that you ever get this sort of knife-edge weir in a practical application. Be sure to measure Cv at low flow for any weir you build or find.

Robert Buxbaum, vote for me for water commissioner. Here are some thoughts on other problems with our drains.

The chemistry of sewage treatment

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The first thing to know about sewage is that it’s mostly water and only about 250 ppm solids. That is, if you boiled down a pot of sewage, only about 1/40 of 1% of it would remain as solids at the bottom of the pot. There would be some dried poop, some bits of lint and soap, the remains of potato peelings… Mostly, the sewage is water, and mostly it would have boiled away. The second thing to know, is that the solids, the bio-solids, are a lot like soil but better: more valuable, brown gold if used right. While our county mostly burns and landfills the solids remnant of our treated sewage, the wiser choice would be to convert it to fertilizer. Here is a comparison between the composition of soil and bio-solids.

The composition of soil and the composition of bio-solid waste. biosolids are like soil, just better.

The composition of soil and the composition of bio-solid waste. biosolids are like soil, just better.

Most of Oakland’s sewage goes to Detroit where they mostly dry and burn it, and land fill the rest. These processes are expensive and engineering- problematic. It takes a lot of energy to dry these solids to the point where they burn (they’re like really wet wood), and even then they don’t burn nicely. As shown above, the biosolids contain lots of sulfur and that makes combustion smelly. They also contain nitrate, and that makes combustion dangerous. It’s sort of like burning natural gun powder.

The preferred solution is partial combustion (oxidation) at room temperature by bacteria followed by conversion to fertilizer. In Detroit we do this first stage of treatment, the slow partial combustion by bacteria. Consider glucose, a typical carbohydrate,

-HCOH- + O2 –> CO2 + H2O.    ∆G°= -114.6 kcal/mol.

The value of ∆G°, is relevant as a determinate of whether the reaction will proceed. A negative value of ∆G°, as above, indicates that the reaction can progress substantially to completion at standard conditions of 25°C and 1 atm pressure. In a sewage plant, many different carbohydrates are treated by many different bacteria (amoebae, paramnesia, and lactobacilli), and the temperature is slightly cooler than room, about 10-15°C, but this value of ∆G° suggests that near total biological oxidation is possible.

The Detroit plant, like most others, do this biological oxidation treatment using either large stirred tanks, of million gallon volume or so, or in flow reactors with a large fraction of cellular-material returning as recycle. Recycle is needed also in the stirred tank process because of the low solid content. The reaction is approximately first order in oxygen, carbohydrate, and bacteria. Thus a 50% cell recycle more or less doubles the speed of the reaction. Air is typically bubbled through the reactor to provide the oxygen, but in Detroit, pure oxygen is used. About half the organic carbon is oxidized and the remainder is sent to a settling pond. The decant (top) water is sent for “polishing” and dumped in the river, while the goop (the bottom) is currently dried for burning or carted off for landfill. The Holly, MI sewage plant uses a heterogeneous reactors for the oxidation: a trickle bed followed by a rotating disk contractor. These have higher bio-content and thus lower area demands and separation costs, but there is a somewhat higher capital cost.

A major component of bio-solids is nitrogen. Much of this in enters the form of urea, NH2-CO-NH2. In an oxidizing environment, bacteria turns the urea and other nitrogen compounds into nitrate. Consider the reaction the presence of washing soda, Na2CO3. The urea is turned into nitrate, a product suitable for gun powder manufacture. The value of ∆G° is negative, and the reaction is highly favorable.

NH2-CO-NH2 + Na2CO3 + 4 O2 –> 2 Na(NO3) + 2 CO2 + 2 H2O.     ∆G° = -177.5 kcal/mol

The mixture of nitrates and dry bio-solids is highly flammable, and there was recently a fire in the Detroit biosolids dryer. If we wished to make fertilizer, we’d probably want to replace the drier with a further stage of bio-treatment. In Wisconsin, and on a smaller scale in Oakland MI, biosolids are treated by higher temperature (thermophilic) bacteria in the absence of air, that is anaerobically. Anaerobic digestion produces hydrogen and methane, and produces highly useful forms of organic carbon.

2 (-HCOH-) –> CO2 + CH4        ∆G° = -33.7 Kcal/mol

3 (-HCOH-) + H2O –> -CH2COOH + CO2 +  2 1/2 H2        ∆G° = -21.9 kcal/mol

In a well-designed plant, the methane is recovered to provide heat to the plant, and sometimes to generate power. In Wisconsin, enough methane is produced to cook the fertilizer to sterilization. The product is called “Milorganite” as much of it comes from Milwaukee and much of the nitrate is bound to organics.

Egg-shaped, anaerobic biosolid digestors.

Egg-shaped, anaerobic biosolid digestors, Singapore.

The hydrogen could be recovered too, but typically reacts further within the anaerobic digester. Typically it will reduce the iron oxide in the biosolids from the brown, ferric form, Fe2O3, to black FeO.  In a reducing atmosphere,

Fe2O3 + H2 –> 2 FeO + H2O.

Fe2O3 is the reason leaves turn brown in the fall and is the reason that most poop is brown. FeO is the reason that composted soil is typically black. You’ll notice that swamps are filled with black goo, that’s because of a lack of oxygen at the bottom. Sulphate and phosphorous can be bound to ferrous iron and this is good for fertilizer. Generally you want the reduction reactions to go no further.

Weir dam on the river dour. Used to manage floods, increase residence time, and oxygenate the flow.

Weir dam on the river Dour in Scotland. Dams of this type increase residence time, and oxygenate the flow. They’re good for fish, pollution, and flooding.

When allowed to continue, the hydrogen produced by anaerobic digestion begins to reduce sulfate to H2S.

NaSO4 + 4.5 H2 –>  NaOH + 3H2O + H2S.

I’m running for Oakland county, MI water commissioner, and one of my aims is to stop wasting our biosolids. Oakland produces nearly 1000,000 pounds of dry biosolids per day. This is either a blessing or a curse depending on how we use it.

Another issue, Oakland county dumps unpasteurized, smelly black goo into Lake St. Clair every other week, whenever it rains more than one inch. I’d like to stop this by separating the storm and “sanitary” sewage. There is a capital cost, but it can save money because we’d no longer have to pay to treat our rainwater at the Detroit sewage plant. To clean the storm runoff, I’d use mini wetlands and weir dams to increase residence time and provide oxygen. Done right, it would look beautiful and would avoid the flash floods. It should also bring natural fish back to the Clinton River.

Robert Buxbaum, May 24 – Sept. 15, 2016 Thermodynamics plays a big role in my posts. You can show that, when the global ∆G is negative, there is an increase in the entropy of the universe.

Weir dams to slow the flow and save our lakes

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As part of explaining why I want to add weir dams to the Red Run drain, and some other of our Oakland county drains, I posed the following math/ engineering problem: if a weir dam is used to double the depth of water in a drain, show that this increases the residence time by a factor of 2.8 and reduces the flow speed by 1/2.8. Here is my solution.

A series of weir dams on Blackman Stream, Maine. Mine would be about as tall, but somewhat further apart.

A series of weir dams on Blackman Stream, Maine. Mine would be about as tall, but wider and further apart. The dams provide oxygenation and hold back sludge.

Let’s assume the shape of the bottom of the drain is a parabola, e.g. y = x2 , and that the dams are spaced far enough apart that their volume is small compared to the volume of water. We now use integral calculus to calculate how the volume of water per mile, V is affected by water height:  V =2XY- ∫ y dx = 2XY- 2/3 X3 =  4/3 Y√Y. Here, capital Y is the height of water in the drain, and capital X is the horizontal distance of the water edge from the drain centerline. For a parabolic-bottomed drain, if you double the height Y, you increase the volume of water per mile by 2√2. That’s 2.83, or about 2.8 once you assume some volume to the dams.

To find how this affects residence time and velocity, note that the dam does not affect the volumetric flow rate, Q (gallons per hour). If we measure V in gallons per mile of drain, we find that the residence time per mile of drain (hours) is V/Q and that the speed (miles per hour) is Q/V. Increasing V by 2.8 increases the residence time by 2.8 and decreases the speed to 1/2.8 of its former value.

Why is this important? Decreasing the flow speed by even a little decreases the soil erosion by a lot. The hydrodynamic lift pressure on rocks or soil is proportional to flow speed-squared. Also, the more residence time and the more oxygen in the water, the more bio-remediation takes place in the drain. The dams slow the flow and promote oxygenation by the splashing over the weirs. Cells, bugs and fish do the rest; e.g. -HCOH- + O2 –> CO2 + H2O. Without oxygen, the fish die of suffocation, and this is a problem we’re already seeing in Lake St. Clair. Adding a dam saves the fish and turns the run into a living waterway instead of a smelly sewer. Of course, more is needed to take care of really major flood-rains. If all we provide is a weir, the water will rise far over the top, and the run will erode no better (or worse) than it did before. To reduce the speed during those major flood events, I would like to add a low bicycle path and some flood-zone picnic areas: just what you’d see on Michigan State’s campus, by the river.

Dr. Robert E. Buxbaum, May 12, 2016. I’d also like to daylight some rivers, and separate our storm and toilet sewage, but those are longer-term projects. Elect me water commissioner.

A run runs through it

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The word ‘run’ appears to be a Michigan dialect for small river. Perhaps Michigan’s most famous run is the Willow run, where the airport is. Currently, almost all of our runs are unrecognizable, they are either trapped in pipes underground, or so dredged out and poisoned that they are more properly called sewers. If I’m elected Oakland county water resources commissioner (drain commissioner) I’d like to free some of these runs, and detoxify them.

These branches of the red run flow beneath the surface of Royal Oak with the main section beneath Vinsetta Blvd.

These branches of the red run flow beneath the surface of Royal Oak with the main section beneath Vinsetta Blvd.

Consider this historical map of Royal Oak. It shows two  river branches, currently under ground. Back in the day, these were known as the north and south branch of the Red run. The south branch is fed by the Washington creek and the small run, now under ground, with the main branch of the run crossing Woodward ave at Catalpa st. These runs only appear above ground in Warren, MI, miles away, as a polluted sewer. But in Royal Oak they should still be clean. If they were partially freed. That is if the channel were exposed to air again to provide small wetlands along the original path — along Vinsetta Blvd, for example. Vinsetta Blvd. already has concrete bridges to show where the run originally ran. The small wetlands would provide habitat for birds and butterflies, and would provide storm relief and some bioremediation as well. After a heavy rain, most of the water would be absorbed into the ground, while the existing pipes carry away the rest.

Robert E. Buxbaum, March 21, 2016

Follow the feces; how to stop the poisoning

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In Oakland county, we regularly poison our basements and our lake St Clair beaches with feces — and potentially our water supply too. We have a combined storm and sanitary sewer system that mixes feces-laden sanitary sewage with rainwater, and our pipes are too old and small to handle the amount of storm water from our larger rains. A group called “Save Lake St. Clair” is up in arms but the current commissioner claims the fault is not his. It’s global warming, he says, and the rains are bigger now. Maybe, or maybe the fault is wealth: more and more of the county is covered by asphalt, so less rain water can soak in the ground. Whatever the cause, the Commissioner should deal with it (I’m running for water commissioner, BTW). As the chart of toxic outfalls shows, we’ve had regular toxic sewage discharges into the Red Run basically every other week, with no exceptional rainfalls: only 0.9″ to 1.42″.

Toxic outfalls into lake St Clair, Feb 20 to Mar 20, 2016. There were also two outfalls into the Rouge in this period. These are too many to claim they are once in hundred-year events.

Toxic outfalls into lake St Clair, Feb 20 to Mar 20, 2016. There were also two outfalls into the Rouge in this period. These are too many to claim they are once in hundred-year events.

Because we have a combined system, the liquid level rises in our sewers whenever it rains. When the level is above the level of a basement floor drain, mixed sewage comes up into the basement. A mix of storm water comes up mixed with poop and anything else you and your neighbors flush down. Mixed sewage can come up even if the sewers were separate, but far less often. Currently most of the dry outfall from our old, combined sewers is sent to Detroit’s Waste Water Treatment plant near Zug Island. When there is a heavy rain, the pipe to Zug is overwhelmed. We avoid flooding your basement every other week by diverting as much as we can of the mixed storm water and septic sewage to lake St. Clair. This is poop, barely treated, and the fishermen and environmentalists hate it.

The beaches along Lake St Clair are closed every other week: whenever the pipes to Detroit start getting overwhelmed, whenever there is about 1″ or rain. Worse yet, the sewage is enters the lake just upstream of the water intake on Belle Isle, see map below. Overflow sewage follows the red lines entering the Clinton River through the GW Kuhn — Red Run Drain or through the North Branch off the River. From there it flows out into Lake St. Clair near Selfridge ANG, generally hugging the Michigan shore of the lake, following the light blue line to poison the metro beaches. it enters the water intake for the majority of Oakland County at the Belle Island water intakes, lower left.

Follow the feces to see why our beeches are polluted. It's just plain incompetence.

The storm water plus septic sewage mix is not dumped raw into lake St. Clair, but it’s nearly raw. The only treatment is to be spritzed with bleach in the Red Run Drain. The result is mats of black gunk with floating turds, toilet paper and tampons. This water is filtered before we drink it, and it’s sprayed with more chlorine, but that’s not OK. We can do much better than this. We don’t have to regularly dump poop into the river just upstream of our water intake. I favor a two-prong solution.

The first, quick solution is to have better pumps to send the sewage to Detroit. This is surprisingly expensive since we still have to treat the rain water. Also it doesn’t take care of the biggest rains; there is a limit to what our pipes will handle, but it stops some basement flooding, and it avoids some poisoning of our beaches and drinking water.

This is our combined sewer system showing a tunnel cistern (yuk) and the outflow into the Red Run. We can do better

A combined sewer system showing a tunnel cistern. Outflow goes into the Red Run. We can do better.

A second, longer term solution is to disentangle the septic from the storm sewers. My approach would be to do this in small steps, beginning by diverting some storm runoff into small wetlands or French drain retention. Separating the sewers this way is cheaper and more environmentally sound than trying to treat the mixed flow in Detroit, and the wetlands and drains would provide pleasant park spaces, but the project will take decades to complete. If done right, this would save quite a lot over sending so much liquid to Detroit, and it’s the real solution to worries about your floor drains back-flowing toxic sludge into your basement.

The incumbent, I fear, has little clue about drainage or bio-treatment. His solution is to build a $40MM tunnel cistern along Middlebelt road. This cistern only holds 3 MM gallons, less than 1/100 of the volume needed for even a moderate rain. Besides, at $13/gallon of storage, it is very costly solution compared to my preference — a French drain (costs about 25¢/gallon of storage). The incumbents cistern has closed off traffic for months between 12 and 13 mile, and is expected to continue for a year, until January, 2017. It doesn’t provide any bio-cleaning, unlike a French drain, and the cistern leaks. Currently groundwater is leaking in. This has caused the lowering of the water table and the closure of private wells. If the leak isn’t fixed , the cistern will leak septic sewage into the groundwater, potentially infecting people for miles around with typhus, cholera, and all sorts of 3rd world plagues.

There is also an explosion hazard to the incumbent’s approach. A tunnel cistern like this blew up near my undergraduate college sending manhole covers flying. This version has much bigger manhole covers: 15′ cement, not 2′ steel. If someone pours gasoline down the drain during a rainstorm and if a match went in later, the result could be deadly. The people building these projects are the same ones who fund the incumbent’s campaign, and I suspect they influenced him for this mis-chosen approach. They are the folks I fear he goes to for engineering advice. If you’d like to see a change for the better. Elect me, Elect an engineer.

Dr. Robert E. Buxbaum, March 26, 2016. Go here to volunteer or contribute.

How to help Flint and avoid lead here.

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As most folks know, Flint has a lead-poisoning problem that seems to have begun in April, 2014 when the city switched its water supply from Detroit-supplied, Lake Huron water to their own source, water from the Flint River. Here are some thoughts on how to help the affected population, and how to avoid a repeat in Oakland county, where I’m running for water commissioner. First observation, it is not enough to make sure that the source water does not contain lead. The people who decided on the switch had found that the Flint river water had no significant content of lead or other obvious toxins. A key problem, it seems: the river water did not contain anticorrosion phosphates, and none, it seems, were added by the Flint water folks. It also seems that insufficient levels of chlorine (hypochlorite) were added. After the switch, citizens started seeing disgusting, brown water come from their taps, and citizens with lead pipes or solder were poisoned with ppb-levels of lead. There was also an outbreak of legionaries disease that killed 12 people. It was the legionaries that alerted the CDC to the possibility of lead, since it seems the water folks were fudging the numbers there, and hiding that part of the problem.

Flint water, Sept 2015, before switching back to Lake Huron.

Flint water after 5 hours of flushing, Sept 2015, before switching back to Lake Huron.

The city began solving its problem by switching back to Detroit-supplied, Lake Huron water in October, 2015. Beginning in December, 2015, they started adding triple doses of phosphate to the wate. As a result, Flint tap-water is now back within EPA standards, but it’s still fairly unsafe, see here for more details.

There has been a fair amount of finger-pointing. At Detroit for raising the price of water so Flint had to switch, at water officials ignoring the early signs of lead and fudging their reports, at other employees for not adding phosphate or enough chlorine, and at “the system” for not providing Flint’s government with better oversight. My take is that a lot of the problem came from the ignorance of the water commission, and it’s commissioner. We elect our water commissioners to be competent overseers of complex infrastructure, but in may counties folks seem to pick them the same way they pick aldermen: for a nice smile, a great handshake, and an ability to remember names. That, anyway, seems to be the way that Oakland got its current water commissioner. When you pick your commissioner that way, it’s no surprise that he (or she) isn’t particularly up on corrosion chemistry, something that few people understand, and fewer care about until it bites them.

Flint river water contains corrosive chloride that probably helped dissolve the lead from pipes and solder. Contributing to the corrosion problem, I’m going to guess that Flint River water also contains, relatively little carbonate, but significant amounts of chelating chemicals, like EDTA, in 10s of ppb concentration. EDTA isn’t poisonous at these concentrations, but it’s common in industry and is the most commonly used antidote for lead poisoning. EDTA extracts lead and other metals from people and would tend to contribute to the process of extracting lead and iron oxide from the pipes surface into the drinking water. With EDTA in the water, a lot of phosphate or hypochlorite would be needed to avoid the lead poisoning problem and the deadly multiplication of disease.

Detroit ex-mayor Kwame Kilpatrick has claimed that both Flint water and Detroit water were known to be poisoned even a decade before the switch. I find these claims believable given the high levels of lead in kids blood even before the switch. Also, I note that there are areas of Detroit where the blood-lead levels are higher than Flint. Flint tested at the taps in a way that fudged the data during the first days of the poisoning, and I suspect many of our MI cities do this today — just to make the numbers look better. My first suggestion therefore is to test correctly, both at the pipes and at the taps; lead pipes are most-often found in the last few feet before the tap. In particular, we should test at all schools and other places where the state has direct authorization to fix the problem. A MI senate bill has been proposed to this effect, but I’m not sure where it stands in the MI house. It seems there are movements to add lots of ‘riders’ and that’s usually a bad sign.

Another thought is that citizens should be encouraged to test their private taps and helped to fix them. The state can’t come in and test or rip out your private pipes, even if they suspect lead, but the private owner has that authorization. The state could condemn a private property where they believe the water is bad, but I doubt they could evict the residents. It’s a democratic republic, as I understand; you have the right to be deadly stupid. But I’ll take my own suggestion to encourage you: If you think your water has lead, take a sample and call (517) 335-8184. Do it.

Another suggestion, perhaps the easiest and most important, is drink bottled water for now, and if you feel you’ve been poisoned, take an antidote.  As I understand things, the state is already providing bottles of imported water. The most common antidote is, as I’d mentioned, EDTA. Assuming that Flint River water had enough EDTA to significantly worsen the problem, the cheapest antidote might be Flint River water, assuming you drew it in lead-free pipes and chlorinated sufficiently to rid it of bugs. If there is EDTA it will help the poisoned. Another antidote is Succinic acid, something sold by REB Research, my company. As with EDTA it is non-toxic, even in fairly large doses, but its use would have to be doctor- approved.

Robert E. Buxbaum, January 19-31, 2016. I hope this helps. We’d have to check Flint River water for levels of EDTA, but I suspect we’d find biologically significant concentrations. If you think Oakland should have an engineer in charge of the water, elect Buxbaum for water commissioner.