Monthly Archives: April 2013

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Some 2-3 years ago I did an interview where I stood inside one of our hydrogen generator shacks (with the generator running) and poked a balloon filled with hydrogen with a lit cigar — twice. No fire, no explosion, either time. It’s not a super hit, but it’s gotten over 5000 views so far. Here it is

New hydrogen generator from REB Research

Here’s the new, latest version of our Me150 hydrogen generator with our wonder-secretary, Libby, shown for scale. It’s smaller and prettier than the previous version shown at left (previous version of Me150, not of secretary). Hydrogen output is 99.9999% pure, 9.5 kg/day, 75 slpm, 150 scfh H2; it generates hydrogen from methanol reforming in a membrane reactor. Pricing is $150,000. Uses about 7 gal of methanol-water ($6 worth) per kg of H2 (380 ft3). Can be used to fill weather balloons, cool electric dynamos, or provide hydrogen fuel for 2-10 fuel cell cars.

New REB Research hydrogen generator 150 scfh of 99.9999% H2 from methanol reforming

New REB Research hydrogen generator 150 scfh of 99.9999% pure H2 from methanol-water reforming against metal membranes.

Dr. Robert E. Buxbaum

Nuclear Power: the elephant of clean energy

As someone who heads a hydrogen energy company, REB Research, I regularly have to tip toe about nuclear power, a rather large elephant among the clean energy options. While hydrogen energy looks better than battery energy in terms of cost and energy density, neither are really energy sources; they are ways to transport energy or store it. Among non-fossil sources (sources where you don’t pollute the air massively) there is solar and wind: basically non-reliable, low density, high cost and quite polluting when you include the damage done making the devices.

Compared to these, I’m happy to report that the methanol used to make hydrogen in our membrane reactors can come from trees (anti-polluting), even tree farming isn’t all that energy dense. And then there’s uranium: plentiful, cheap and incredibly energy dense. I try to ignore how energy dense uranium is, but the cartoon below shows how hard that is to do sometimes. Nuclear power is reliable too, and energy dense; a small plant will produce between 500 and 1000 MW of power; your home uses perhaps 2 kW. You need logarithmic graph paper just to compare nuclear power to most anything else (including hydrogen):

log_scale

A tiny amount of uranium-oxide, the size of a pencil will provide as much power as hundreds of train cars full of coal. After transportation, the coal sells for about $80/ton; the sells for about $25/lb: far cheaper than the train loads of coal (there are 100-110 tons of coal to a train-car load). What’s more, while essentially all of the coal in a train car ends up in the air after it’s burnt, the waste uranium generally does not go into the air we breathe. The coal fumes are toxic, containing carcinogens, carbon monoxide, mercury, vanadium and arsenic; they are often radioactive too. All this is avoided with nuclear power unless there is a bad accident, and bad accidents are far rarer with nuclear power than, for example, with natural gas. Since Germany started shutting nuclear plants and replacing them with coal, it appears they are making all of Europe sicker).

It is true that the cost to build a nuclear plant is higher than to build a coal or gas plant, but it does not have to be: it wasn’t that way in the early days of nuclear power, nor is this true of military reactors that power our (USA) submarines and major warships. Commercial nuclear reactors cost a lot largely because of the time-cost for neighborhood approval (and they don’t always get approval). Batteries used for battery power get no safety review generally though there were two battery explosions on the Dreamliner alone, and natural gas has been known to level towns. Nuclear reactors can blow up too, as Chernobyl showed (and to a lesser extent Fukushima), but almost any design is better than Chernobyl.

The biggest worry people have with nuclear, and the biggest objection it seems to me, is escaped radiation. In a future post, I plan to go into the reality of the risk in more detail, but the worry is far worse than the reality, or far worse than the reality of other dangers (we all die of something eventually). The predicted death rate from the three-mile island accident is basically nil; Fukushima has provided little health damage (not that it’s a big comfort). Further, bizarre as this seems the thyroid cancer rate in Belarus in the wind-path of the Chernobyl plant is actually slightly lower than in the US (7 per 100,000 in Belarus compared to over 9 per 100,000 in the USA). This is clearly a statistical fluke; it’s caused, I believe, by the tendency for Russians to die of other things before they can get thyroid cancer, but it suggests that the health risks of even the worst nuclear accidents are not as bad as you might think. (BTW, Our company makes hydrogen extractors that make accidents less likely)

The biggest real radiation worry (in my opinion) is where to put the waste. Ever since President Carter closed off the option of reprocessing used fuel for re-use there has been no way to permanently get rid of waste. Further, ever since President Obama closed the Yucca Mountain burial repository there have been no satisfactory place to put the radioactive waste. Having waste sitting around above ground all over the US is a really bad option because the stuff is quite toxic. Just as the energy content of nuclear fuel is higher than most fuels, the energy content of the waste is higher. Burying it deep below a mountain in an area were no-one is likely to live seems like a good solution: sort of like putting the uranium back where it came from. And reprocessing for re-use seems like an even better solution since this gets rid of the waste permanently.

I should mention that nuclear power-derived electricity is a wonderful way to generate electricity or hydrogen for clean transportation. Further, the heat of hot springs comes from nuclear power. The healing waters that people flock to for their health is laced with isotopes (and it’s still healthy). For now, though I’ll stay in the hydrogen generator business and will ignore the clean elephant in the room. Fortunately there’s hardly any elephant poop, only lots and lots of coal and solar poop.

 

Science is the Opposite of Religion

Some years ago, my daughter came back from religions school and asked for a definition of science. I told her that science was the opposite of religion. I didn’t mean to insult religion or science; the big bang for one thing, strongly suggests there is a God -creator, and quantum mechanics suggests (to me) that there is a God -maintainer, but religion deals with other things beyond a belief in God, and I meant to point out that every basic of how science looks at things finds its opposite in religion.

Science is based on reproducibility and lack of meaning: if you do the same experiment over and over, you’ll always get the same result as you did before and the same result as anyone else — when the results are measured to some good, statistical norm. The meaning for the observation? that’s a meaningless question. Religion is based on the centrality of drawing meaning, and the centrality of non-reproducible, one-time events: creation, the exodus from Egypt, the resurrection of Jesus, the birth of Zeus, etc. A religious believer is one who changes his or her life based on the lesson of these; to him, a non-believer is one who draws no meaning, or needs reproducible events.

Science also requires that anyone will get the same result if they do the same process. Thus, chemistry class results don’t depend on the age, sex, or election of the students. Any student who mixes the prescribed two chemicals and heats to a certain temperature is expected to get the same result. The same applies to measures of the size of the universe, or its angular momentum or age. In religion, it is fundamentally important what sex you are, how old you are, who your parents were, or what you are thinking at the time. If the right person says “hoc es corpus” over wine and wafers, they change; if not, they do not. If the right person opens the door to heaven, or closes it, it matters in religion.

A main aspect of all religion is prayer; the idea that what you are thinking or saying changes things on high and here below. In science, we only consider experiments where the words said over the experiment have no effect. Another aspect of religion is tchuvah (regret, repentance); the idea is that thoughts can change the effect of actions, at least retroactively. Science tends to ignore repentance, because they lack the ability to measure things that work backwards in time, and because the scientific instruments we have currently do not take measurements on the soul to see if the repentance had any effect. Basically, the science-universe is only populated with those things which can be measured or reproducibly affected, and that pretty much excludes the soul. That the soul does not exist in the science universe doesn’t mean it doesn’t exist.

Another main aspect of religion is morality: you’re supposed to do the right thing. Morality varies from one religion to another, and you may think the other fellow’s religion has a warped morality, but at least there is one in all religions. In science, for better or worse, there is no apparent morality, either to man or to the universe. Based on science, the universe will end, either by a bang or a whimper, and in that void of end it would seem that killing a mouse is about as important as killing a person. No religion I know of sees the universe ending in either cold or hot death; as a result. Consistent with this, they all see murder is a sin against God. This difference is a big plus for religion, IMHO. That man sees murder as a true evil is either a sign that religion is true, or that it isn’t depending on the value you put on life. Another example of the moral divide: Scientists, especially academics, tend to be elitists. Their morality, such as it is, values great minds and great projects over the humble and stupid. Classical religion sees the opposite; it promoting the elevation of the poor, weak, and humble. There is no fundamental way to tell which one is right, and I tend to think that both are right in their own, mirror-image universes.

It is now worthwhile to consider what each universe sees as wisdom. An Explanation in the universe of science has everything to do with utility and not any internal sense of having understood, as such. I understand something only to the extent I predict that thing or can do something based on the knowledge. in religion, the motivation for all activity is always just understanding — typically of God on the bone-deep level. This difference shows up very clearly in dealing with quantum mechanics. To a scientist, the quantum world is fundamentally a door from religion because it is basically non-understandable but very useful. Religion totally ignores quantum mechanics for the same reason: it’s non-understandable, but very precise and useful. Anything you can’t understand is meaningless to them (literally), and useful is mostly defined in terms of building the particular religion; I think this is a mistake on many levels. I note that looking for disproof is the glory-work of all science development, but the devil’s work of every religion. A religious leader will grab on to statistical findings that suggest that his type of prayer cures people, but will always reject disproof, e.g. evidence that someone else’s prayers works better, or that his prayer does nothing at all. Each religion is thus in a war with the other, each trying to build belief, while not removing it. Science is the opposite. Religion starts with the answer and accepts any support it can; fundamental change is considered a bad thing in religion. The opposite is so with science; disproof is considered “progress,” and change is good.

These are not minor aspects of science and religion, by the way, but these are the fundamental basics of each, as best I can tell. History, politics, and psychology seem to be border-line areas, somewhere between science and religion. The differences do not reflect a lack in these fields, but just a recognition that each works according to its own logic and universe.

My hope in life is to combine science and religion to the extent possible, but find that supporting science in any form presents difficulties when I have to speak to others in the religious community, my daughter’s teachers among them. As an example of the problem that come up, my sense is that the big bang is a fine proof of creation and should be welcomed by all (most) religious people. I think its a sign that there is a creator when science says everything came from nothing, 14,000,000 years ago. Sorry to say, the religious leaders I’ve met reject the big bang, and claim you can’t believe in anything that happened 14,000,000,000 years ago. So long as science shows no evidence of a bearded observer at the center, they are not interested. Scientists, too have trouble with the bang, I find. It’s a one-time event that they can’t quite explain away (Steven Hawking keeps trying). The only sane approach I’ve found is to keep blogging, and otherwise leave each to its area. There seems to be little reason to expect communal agreement.

by Robert E. Buxbaum, Apr. 7, 2013. For some further thoughts, see here.

The Gift of Chaos

Many, if not most important engineering systems are chaotic to some extent, but as most college programs don’t deal with this behavior, or with this type of math, I thought I might write something on it. It was a big deal among my PhD colleagues some 30 years back as it revolutionized the way we looked at classic problems; it’s fundamental, but it’s now hardly mentioned.

Two of the first freshman engineering homework problems I had turn out to have been chaotic, though I didn’t know it at the time. One of these concerned the cooling of a cup of coffee. As presented, the coffee was in a cup at a uniform temperature of 70°C; the room was at 20°C, and some fanciful data was presented to suggest that the coffee cooled at a rate that was proportional the difference between the (changing) coffee temperature and the fixed room temperature. Based on these assumptions, we predicted exponential cooling with time, something that was (more or less) observed, but not quite in real life. The chaotic part in a real cup of coffee, is that the cup develops currents that move faster and slower. These currents accelerate heat loss, but since they are driven by the temperature differences within the cup they tend to speed up and slow down erratically. They accelerate when the cup is not well stirred, causing new stir, and slow down when it is stirred, and the temperature at any point is seen to rise and fall in an almost rhythmic fashion; that is, chaotically.

While it is impossible to predict what will happen over a short time scale, there are some general patterns. Perhaps the most remarkable of these is self-similarity: if observed over a short time scale (10 seconds or less), the behavior over 10 seconds will look like the behavior over 1 second, and this will look like the behavior over 0.1 second. The only difference being that, the smaller the time-scale, the smaller the up-down variation. You can see the same thing with stock movements, wind speed, cell-phone noise, etc. and the same self-similarity can occur in space so that the shape of clouds tends to be similar at all reasonably small length scales. The maximum average deviation is smaller over smaller time scales, of course, and larger over large time-scales, but not in any obvious way. There is no simple proportionality, but rather a fractional power dependence that results in these chaotic phenomena having fractal dependence on measure scale. Some of this is seen in the global temperature graph below.

Global temperatures measured from the antarctic ice showing stable, cyclic chaos and self-similarity.

Global temperatures measured from the antarctic ice showing stable, cyclic chaos and self-similarity.

Chaos can be stable or unstable, by the way; the cooling of a cup of coffee was stable because the temperature could not exceed 70°C or go below 20°C. Stable chaotic phenomena tend to have fixed period cycles in space or time. The world temperature seems to follow this pattern though there is no obvious reason it should. That is, there is no obvious maximum and minimum temperature for the earth, nor any obvious reason there should be cycles or that they should be 120,000 years long. I’ll probably write more about chaos in later posts, but I should mention that unstable chaos can be quite destructive, and quite hard to prevent. Some form of chaotic local heating seems to have caused battery fires aboard the Dreamliner; similarly, most riots, famines, and financial panics seem to be chaotic. Generally speaking, tight control does not prevent this sort of chaos, by the way; it just changes the period and makes the eruptions that much more violent. As two examples, consider what would happen if we tried to cap a volcano, or provided  clamp-downs on riots in Syria, Egypt or Ancient Rome.

From math, we know some alternate ways to prevent unstable chaos from getting out of hand; one is to lay off, another is to control chaotically (hard to believe, but true).